Small cavitands specifically binding a water molecule

Ihm, C; In, Y; Park, Y; Paek, K

doi:10.1021/ol036206x

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Small cavitands specifically binding a water molecule

Ihm, C;
In, Y;
Park, Y;
Paek, K

Citations

WEB OF SCIENCE

16

Citations

SCOPUS

19

초록

Three new C-2v cavitands based on resorcin[4]arene bind water specifically at low temperature in CD2Cl2 or CDCl3 due to their complementarity to water as well as the solvophobic interaction. The averaged AHdegrees and ASdegrees values are -2.3 kcal mol(-1) and -128 cal mol(-1) K-1, which gave the averaged -AGdegrees of 1.9 kcal mol(-1) at -50degreesC in water saturated CD2Cl2.

키워드

FACILE SYNTHESIS; HOST

제목: Small cavitands specifically binding a water molecule

저자: Ihm, C; In, Y; Park, Y; Paek, K

DOI: 10.1021/ol036206x

발행일: 2004-02-05

유형: Article

저널명: Organic Letters

권: 6

호: 3

페이지: 369 ~ 372