TiO2@carbon Core-Shell Nanostructure Electrodes for Improved Electrochemical Properties in Alkaline Solution

  • Do-Young Kim; 
  • 이영우; 
  • Sang-Beom Han; 
  • A-Ra Ko; 
  • Hyun-Su Kim; 
  • ... 박경원; 
  • 외 2명

초록

We report nanostructure electrodes with TiO2 as a core and carbon as a shell (TiO2@C) for oxygen reduction in alkaline solution. The structure of core-shell electrodes is characterized by transmission electron microscopy, Raman spectroscopy, X-ray diffraction method, and X-ray photoelectron microscopy. The electrochemical properties of the TiO2@C electrodes are characterized using a potentiostat and compared with those of carbon supported Pt catalyst. In particular, the core-shell electrode with dominant pyridinic-N component exhibits an imporved electrocatalytic activity for oxygen reduction reaction in alkaline solution.

키워드

Nanostructure materials; Core/shell; N-doping; Oxygen reduction reaction
제목
TiO2@carbon Core-Shell Nanostructure Electrodes for Improved Electrochemical Properties in Alkaline Solution
저자
Do-Young Kim; 이영우; Sang-Beom Han; A-Ra Ko; Hyun-Su Kim; Si-Jin Kim; 오상은; 박경원
DOI
10.5229/JKES.2012.15.2.90
발행일
2012-05
저널명
전기화학회지
권
15
호
2
페이지
90 ~ 94