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Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit
- Jeong, Kyung Seok;
- Lee, Bo Hyung;
- Li, Qiaowei;
- Choi, Sang Beom;
- Kim, Jaheon;
- 외 1명
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10초록
A near identical MOF from the reaction between a homochiral ligand and La-III ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.
키워드
COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; RETICULAR SYNTHESIS; CHIRAL RECOGNITION; CRYSTAL; CRYSTALLIZATION; CYCLODEXTRINS; RESOLUTION; CATALYSIS; TARTRATES
- 제목
- Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit
- 저자
- Jeong, Kyung Seok; Lee, Bo Hyung; Li, Qiaowei; Choi, Sang Beom; Kim, Jaheon; Jeong, Nakcheol
- 발행일
- 2011
- 유형
- Article
- 저널명
- CrystEngComm
- 권
- 13
- 호
- 5
- 페이지
- 1277 ~ 1279
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 3 페이지
- ISSN
- P 1466-8033