Two porous metal-organic frameworks containing zinc-calcium clusters and calcium cluster chains

Noh, Kyungkyou; Ko, Nakeun; Park, Hye Jeong; Park, SangYoun; Kim, Jaheon

doi:10.1039/c4ce01237b

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Two porous metal-organic frameworks containing zinc-calcium clusters and calcium cluster chains

Noh, Kyungkyou;
Ko, Nakeun;
Park, Hye Jeong;
Park, SangYoun;
Kim, Jaheon

Citations

WEB OF SCIENCE

30

Citations

SCOPUS

31

초록

A two-dimensional metal-organic framework (MOF) containing both Zn(II) and Ca(II) centres and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (BET 1560 and 914 m(2) g(-1), respectively) among the reported Ca-based MOFs and also exhibit high gas uptake up to 1 bar for H-2 at 77 K and CO2 at 298 K.

키워드

GAS-ADSORPTION; COORDINATION POLYMERS; PROTON CONDUCTIVITY; CRYSTAL-STRUCTURES; THERMAL-STABILITY; SINGLE-CRYSTAL; LIGAND; POROSITY; NETWORK; MOF

제목: Two porous metal-organic frameworks containing zinc-calcium clusters and calcium cluster chains

저자: Noh, Kyungkyou; Ko, Nakeun; Park, Hye Jeong; Park, SangYoun; Kim, Jaheon

DOI: 10.1039/c4ce01237b

발행일: 2014

유형: Article

저널명: CrystEngComm

권: 16

호: 37

페이지: 8664 ~ 8668

출판사: ROYAL SOC CHEMISTRY

발행국가: 영국

분량: 5 페이지

ISSN: P 1466-8033