Homochiral 3D metal-organic frameworks from chiral 1D rods: 6-way helical packing

  • Shin, Sung Min; 
  • Moon, Dohyun; 
  • Jeong, Kyung Seok; 
  • Kim, Jaheon; 
  • Thallapally, Praveen K.; 
  • 외 1명
Citations

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SCOPUS

22

초록

The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is sensitively dependent on the dimension of SBBs. In addition, we were able to identify a new plywood-like network from ligand 2H(2) exhibiting an unprecedented six-way chiral helical packing motif, which extends the list of invariant rod packings.

키워드

SINGLE-CRYSTAL TRANSFORMATIONS; BUILDING-BLOCKS; ASYMMETRIC CATALYSIS; RETICULAR SYNTHESIS; COMPLEX; NETWORKS
제목
Homochiral 3D metal-organic frameworks from chiral 1D rods: 6-way helical packing
저자
Shin, Sung Min; Moon, Dohyun; Jeong, Kyung Seok; Kim, Jaheon; Thallapally, Praveen K.; Jeong, Nakcheol
DOI
10.1039/c1cc12908b
발행일
2011
유형
Article
저널명
Chemical Communications
권
47
호
33
페이지
9402 ~ 9404