Highly efficient low-oxidation-potential electrochemiluminescence of ruthenium(II) complex containing selone moiety

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초록

A newly designed ruthenium(II) complex (Ru-Se) bearing a selone moiety showed unexpected enhancement in low-oxidation-potential (LOP) electrochemiluminescence (ECL) observed at electrode potentials before the oxidation of Ru-Se in the presence of tri-n-propylamine (TPrA), which was primarily attributed to the heavy atom effect caused by the selone in Ru-Se. © 2019

키워드

Electrochemiluminescence; Heavy atom effect; Low-oxidation-potential; Ruthenium(II) complex; Selone moiety
제목
Highly efficient low-oxidation-potential electrochemiluminescence of ruthenium(II) complex containing selone moiety
저자
Ju, Y.; Park, H.-J.; Shin, I.-S.; Chung, Y.K.; Kim, J.
DOI
10.1016/j.inoche.2019.05.033
발행일
2019-08
유형
Article
저널명
Inorganic Chemistry Communications
권
106
페이지
86 ~ 90