Color-Tunable Electrogenerated Chemiluminescence of Ruthenium N-Heterocyclic Carbene Complexes

  • Park, Hee-Jun; 
  • Yoo, Sangwook; 
  • Shin, Ik-Soo; 
  • Chung, Young Keun; 
  • Kim, Joohoon
Citations

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초록

Ru(II) complexes 13 bearing various N-heterocyclic carbene (NHC) ligands were synthesized, and their photophysical, electrochemical, and electrogenerated chemiluminescence (ECL) properties were discussed to evaluate a potential of their use as multicolor ECL labels. Interestingly, they exhibited ECL emission ranging from greenish-yellow to red both in nonaqueous and mixed aqueous solutions, which might show the potential of the Ru(II) complexes as multicolor ECL labels.

키워드

Electrogenerated chemiluminescence (ECL); Ruthenium complex; N-Heterocyclic carbene (NHC) ligands; Green ECL emitter; RU(II) COMPLEXES; ELECTROCHEMILUMINESCENCE DETECTION; LIGANDS; SYSTEMS; LUMINESCENT
제목
Color-Tunable Electrogenerated Chemiluminescence of Ruthenium N-Heterocyclic Carbene Complexes
저자
Park, Hee-Jun; Yoo, Sangwook; Shin, Ik-Soo; Chung, Young Keun; Kim, Joohoon
DOI
10.1002/elan.201200619
발행일
2013-05
유형
Article
저널명
Electroanalysis
권
25
호
5
페이지
1111 ~ 1115