Microwave-Assisted Glycolysis for PET with Highly Hydrophilic Surface

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초록

PET fabric with highly hydrophilic surface was obtained by microwave-assisted, nonaqueous glycolysis under alkali condition. Surface hydrophilicity was measured by water drop test, vertical wicking test, and contact angle measurement. At 120 s of irradiation, the glycolyzed PET showed instantaneous wetting with a low level of alkali concentration, such as 0.1% NaOH. DSC and SEM analyses were used to investigate thermal and topological characteristics of the glycolyzed PET. Depending on the required hydrophilicity, the level of alkali and irradiation time must be adjusted. Use of microwave-assisted modification could reduce the treatment time to less than 180 s from 1 to 2 h in a conventional dyeing machine treatment, allowing considerable savings in energy and processing costs.

키워드

POLYETHYLENE TEREPHTHALATEPOLY(ETHYLENE-TEREPHTHALATE) WASTEFILMSDEPOLYMERIZATIONLIQUID
제목
Microwave-Assisted Glycolysis for PET with Highly Hydrophilic Surface
저자
Cho, Jae YeounHong, Cheol-JaeChoi, Hyung-Min
DOI
10.1021/ie302732g
발행일
2013-02-13
유형
Article
저널명
Industrial and Engineering Chemistry Research
52
6
페이지
2309 ~ 2315