Connection of zinc paddle-wheels in a pto-type metal-organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

Ko, Nakeun; Noh, Kyungkyou; Sung, Siyoung; Park, Hye Jeong; Park, Sang Youn; Kim, Jaheon

doi:10.1039/c4cc01501k

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Connection of zinc paddle-wheels in a pto-type metal-organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

Ko, Nakeun;
Noh, Kyungkyou;
Sung, Siyoung;
Park, Hye Jeong;
Park, Sang Youn;
... Kim, Jaheon

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WEB OF SCIENCE

9

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9

초록

A microporous metal-organic framework (mIm-MOF-14) has doubly interpenetrated anionic frameworks resulting from 2-methylimidazolate linking Zn(II) paddle-wheels of charge-neutral pto-type networks, and allows the inclusion of tetramethylammonium ion to exert an enhanced CO2 affinity.

키워드

SINGLE-CRYSTAL TRANSFORMATION; HYDROGEN UPTAKE; BUILDING UNITS; LARGE PORES; LIGAND; CLUSTERS; EXCHANGE; DESIGN; MOF

제목: Connection of zinc paddle-wheels in a pto-type metal-organic framework with 2-methylimidazolate and subsequent incorporation of charged organic guests

저자: Ko, Nakeun; Noh, Kyungkyou; Sung, Siyoung; Park, Hye Jeong; Park, Sang Youn; Kim, Jaheon

DOI: 10.1039/c4cc01501k

발행일: 2014

유형: Article

저널명: Chemical Communications

권: 50

호: 51

페이지: 6785 ~ 6788

출판사: ROYAL SOC CHEMISTRY

발행국가: 영국

분량: 4 페이지

ISSN: E 1364-548X
P 1359-7345