Mesoporous Spinel LiMn2O4 Nanomaterial as a Cathode for High-Performance Lithium Ion Batteries

초록

We demonstrate mesoporous spinel LiMn2O4 nanomaterial (NS-LMO) synthesized by polymer template method for high-performance lithium ion batteries. The as-synthesized NS-LMO exhibits complete spinel LMO structure with dominant {111} surfaces, nanocrystalline of similar to 30 nm in size, and relatively high surface area (similar to 13.8 m(2) g(-1)) with mesoporous characteristics. In contrast, the LMO (SS-LMO) prepared by the solid state reaction method consists of a spinel structure of LMO and an extra phase of Mn2O3. The NS-LMO displays much higher capacity of similar to 96.19 mAh g(-1) at 1 C compared to the SS-LMO (similar to 57.03 mAh g(-1)) and improved rate cycling performance with the complete capacity retention.

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