Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates

Jung, Cheolwon; Choi, Sang Beom; Park, Jaewoo; Jung, Minji; Kim, Jonghoon; Oh, Hyunchul; Kim, Jaheon

doi:10.1039/d2cc06797h

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Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates

Jung, Cheolwon;
Choi, Sang Beom;
Park, Jaewoo;
Jung, Minji;
Kim, Jonghoon;
... Kim, Jaheon;
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초록

Cu(ii)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm)(2) (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 & ANGS; cylindrical pores that can adsorb H-2 gas, and Cu-ZIF-rho has 19.8 & ANGS; cages with a BET surface area of 1320 m(2) g(-1).

제목: Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates

저자: Jung, Cheolwon; Choi, Sang Beom; Park, Jaewoo; Jung, Minji; Kim, Jonghoon; Oh, Hyunchul; Kim, Jaheon

DOI: 10.1039/d2cc06797h

발행일: 2023-03

유형: Article; Early Access

저널명: Chemical Communications

권: 59

호: 27

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