One-Step Synthesis of Hexapod Pt Nanoparticles Deposited on Carbon Black for Improved Methanol Electrooxidation

  • Kwak, Da-Hee; 
  • Lee, Young-Woo; 
  • Lee, Kyung-Hoon; 
  • Park, Ah-Reum; 
  • Moon, Je-Suk; 
  • ... Park, Kyung-Won
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초록

We report hexapod Pt nanoparticles (Hexa-Pt/C) deposited on carbon black synthesized by means of polyol process in the presence of poly(vinyl pyrrolidone) and NO3- and Fe3+ as additives. The Hexa-Pt/C shows nanosized pods grown along {111} facets observed by transmission electron microscopy. For methanol electrooxidation, the Hexa-Pt/C exhibited much improved electrocatalytic activity and stability due to a particular surface exposure favorable for catalytic reaction in comparison with commercial polycrystalline Pt catalyst.

키워드

Hexapod; Pt; Electrocatalyst; Methanol; Electrooxidation; PLATINUM NANOCRYSTALS; DIRECT OXIDATION; CATALYSTS; CHEMISTRY
제목
One-Step Synthesis of Hexapod Pt Nanoparticles Deposited on Carbon Black for Improved Methanol Electrooxidation
저자
Kwak, Da-Hee; Lee, Young-Woo; Lee, Kyung-Hoon; Park, Ah-Reum; Moon, Je-Suk; Park, Kyung-Won
발행일
2013-04
유형
Article
저널명
International Journal of Electrochemical Science
권
8
호
4
페이지
5102 ~ 5107