Electrocatalytic Oxidation Reactions of Pt Hexapod Nanoparticles

  • Kwak, Da-Hee; 
  • Lee, Young-Woo; 
  • Han, Sang-Beom; 
  • Lee, Jin-Yeon; 
  • Zhoh, Choon-Koo; 
  • ... Park, Kyung-Won
Citations

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5
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5

초록

The Pt nanoparticles were synthesized using a polyol process in the presence of additives such as FeCl3, NaNO3, and PVP. In particular, the Pt nanoparticles with a hexapod structure (Pt-FNP) were formed without agglomeration in the presence of additive ions of Fe3+ and NO3- with PVP. The Pt-FNP exhibited an improved electrocatalytic activity for electro-oxidation reactions of methanol, ethanol, and formic acid due to dominant {111} facets formed as a result of a slow growth rate during the chemical process. (C) 2015 Elsevier Ltd. All rights reserved.

키워드

Pt; Hexapod; Nanoparticles; Electro-oxidation reactions; FORMIC-ACID ELECTROOXIDATION; SHAPE-CONTROLLED SYNTHESIS; ELECTROLYTE FUEL-CELL; HIGH-INDEX FACETS; METHANOL ELECTROOXIDATION; ETHANOL ELECTROOXIDATION; PLATINUM NANOCRYSTALS; POLYOL SYNTHESIS; ETHYLENE-GLYCOL; ALLOY NANOPARTICLES
제목
Electrocatalytic Oxidation Reactions of Pt Hexapod Nanoparticles
저자
Kwak, Da-Hee; Lee, Young-Woo; Han, Sang-Beom; Lee, Jin-Yeon; Zhoh, Choon-Koo; Park, Kyung-Won
DOI
10.1016/j.electacta.2015.07.075
발행일
2015-09-10
유형
Article
저널명
Electrochimica Acta
권
176
페이지
790 ~ 796