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Electrocatalytic Oxidation Reactions of Pt Hexapod Nanoparticles
- Kwak, Da-Hee;
- Lee, Young-Woo;
- Han, Sang-Beom;
- Lee, Jin-Yeon;
- Zhoh, Choon-Koo;
- ... Park, Kyung-Won
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5초록
The Pt nanoparticles were synthesized using a polyol process in the presence of additives such as FeCl3, NaNO3, and PVP. In particular, the Pt nanoparticles with a hexapod structure (Pt-FNP) were formed without agglomeration in the presence of additive ions of Fe3+ and NO3- with PVP. The Pt-FNP exhibited an improved electrocatalytic activity for electro-oxidation reactions of methanol, ethanol, and formic acid due to dominant {111} facets formed as a result of a slow growth rate during the chemical process. (C) 2015 Elsevier Ltd. All rights reserved.
키워드
Pt; Hexapod; Nanoparticles; Electro-oxidation reactions; FORMIC-ACID ELECTROOXIDATION; SHAPE-CONTROLLED SYNTHESIS; ELECTROLYTE FUEL-CELL; HIGH-INDEX FACETS; METHANOL ELECTROOXIDATION; ETHANOL ELECTROOXIDATION; PLATINUM NANOCRYSTALS; POLYOL SYNTHESIS; ETHYLENE-GLYCOL; ALLOY NANOPARTICLES
- 제목
- Electrocatalytic Oxidation Reactions of Pt Hexapod Nanoparticles
- 저자
- Kwak, Da-Hee; Lee, Young-Woo; Han, Sang-Beom; Lee, Jin-Yeon; Zhoh, Choon-Koo; Park, Kyung-Won
- 발행일
- 2015-09-10
- 유형
- Article
- 권
- 176
- 페이지
- 790 ~ 796